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TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE

Product Name
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
CAS No.
370-69-4
Chemical Name
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
Synonyms
TTFP;Phosphite, tris(2,2,2-trifluoroethyl);Tris(2,2,2-trifluoroethyl) phosphite 99%;TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE;Ethanol, 2,2,2-trifluoro-, phosphite (3:1);TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE, 99 %
CBNumber
CB7449383
Molecular Formula
C6H6F9O3P
Formula Weight
328.07
MOL File
370-69-4.mol
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TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Property

Boiling point:
130-131 °C743 mm Hg(lit.)
Density 
1.487 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.324(lit.)
Flash point:
>230 °F
BRN 
1714041
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
10-21
HS Code 
2920290090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
270954
Product name
Tris(2,2,2-trifluoroethyl) phosphite
Purity
99%
Packaging
25g
Price
$172
Updated
2024/03/01
Sigma-Aldrich
Product number
270954
Product name
Tris(2,2,2-trifluoroethyl) phosphite
Purity
99%
Packaging
100g
Price
$311.4
Updated
2024/03/01
TRC
Product number
T876718
Product name
Tris(2,2,2-trifluoroethyl) phosphite
Packaging
1g
Price
$60
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0067306
Product name
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
Purity
95.00%
Packaging
25G
Price
$1200.62
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0067306
Product name
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
Purity
95.00%
Packaging
100G
Price
$2783.87
Updated
2021/12/16
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TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Chemical Properties,Usage,Production

Uses

Tris(2,2,2-trifluoroethyl) phosphite was used in the synthesis of N-methoxy-N-methyl bis(2,2,2-trifluoroethyl)phosphonamide via the Arbuzov reaction with 2-bromo-N-methoxy-N-methylacetamide.

Purification Methods

Fractionate it through a 10inch Helipak column [Krogh et al. J Org Chem 19 1124 1954]. Tris-[(3-trifluoromethylhydroxymethylene)-d-camphorato] europium (III) [Eu(tfc)3] [34830-11-0] M 893.6, m 195-299o (dec), ~220o, [ ] D +152o (c 2, CCl4, and varies markedly with concentration). Purify it by extraction with pentane, filter and the filtrate is evaporated and the residual bright yellow amorphous powder is dried at 100o/0.1mm for 36hours. A sample purified by fractional molecular distillation at 180-200o/0.004mm gave a liquid which solidified and softened at ~130o, and melted at ~180o and was analytically pure. IR (CCl4) 1630-1680cm-1 and NMR (CCl4) broad: -1.3 to 0.5, -0.08 (s), 0.41 max (s), 1.6-2.3 and 3.39 (s). [McCreary et al. J Am Chem Soc 96 1038 1974, Goering et al. J Am Chem Soc 93 5913 1971.]

TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Suppliers

Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57511
Advantage
58
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View Lastest Price from TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Tris(2,2,2-trifluoroethyl) phosphite 370-69-4
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50 tons
Release date
2020-01-17
Career Henan Chemical Co
Product
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE 370-69-4
Price
US $7.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100KG
Release date
2018-12-17

370-69-4, TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITERelated Search:


  • Phosphite, tris(2,2,2-trifluoroethyl)
  • TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
  • TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE, 99 %
  • Tris(2,2,2-trifluoroethyl) phosphite 99%
  • TTFP
  • Ethanol, 2,2,2-trifluoro-, phosphite (3:1)
  • 370-69-4
  • C6H6F9O3P
  • CF3CH2O3P
  • Building Blocks
  • Phosphorus Compounds
  • Organic Phosphates/Phosphites
  • Organic Building Blocks
  • Organic Building Blocks
  • Organic Phosphates/Phosphites
  • Phosphorus Compounds